In a medium saucepan, combine water, sugar, cocoa powder, and a pinch of salt. Heat over medium heat, stirring until the sugar is completely dissolved.
Add the finely chopped chili and dark chocolate. Stir until the chocolate is completely melted and the mixture is smooth.
Remove from heat and let the mixture cool slightly. Stir in the fresh lime juice.
Pour the mixture into a shallow dish and place in the freezer.
Every 30 minutes, scrape the sorbet with a fork to break up the ice crystals and create a flaky texture. Repeat this process 3-4 times, or until the sorbet is fully frozen.
Before serving, let the sorbet sit at room temperature for 5 minutes to soften slightly and make it easier to scoop. Garnish with fresh chili slices and a little grated dark chocolate, if desired.
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