In a medium bowl, combine the ricotta cheese and powdered sugar. Using a hand mixer or stand mixer, beat until smooth and creamy. Tip: If the ricotta is too wet, drain it beforehand to ensure a thicker cream.
Add the coffee liqueur, instant coffee, and vanilla extract to the ricotta mixture. Mix thoroughly until a smooth and homogenous cream forms. Tip: Dissolve the instant coffee in a few drops of water beforehand for a more intense flavor.
Melt the dark chocolate over a double boiler or in the microwave at a low setting, being careful not to burn it. Tip: Stir in a few drops of oil for a shinier finish.
Using a piping bag, fill the cooled and dry cannoli shells with the coffee liqueur cream. Fill from both ends to ensure the cream reaches the middle. Tip: Make sure the cream is well-chilled for easier handling and to help it hold its shape.
Drizzle the filled cannoli with the melted chocolate using a small spoon or fork, then sprinkle a little cocoa powder on top. Tip: If you want to decorate them further, you can grate a little chocolate on top just before serving.
Serve the cannoli chilled, on a rustic platter or plate. Tip: Don't fill them too far in advance to prevent the shells from becoming soggy – filling them about 1 hour before serving is ideal.
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