Prepare the chicken thighs. Cut the chicken into bite-sized pieces and combine them in a bowl with the soy sauce, rice vinegar, sesame oil, and brown sugar. Marinate the chicken for at least 30 minutes, allowing the flavors to meld together.
Peel and finely grate the garlic and fresh ginger. Thinly slice the green onions.
Heat the sesame oil in a skillet over medium heat. Add the garlic and ginger and sauté for one to two minutes, or until fragrant.
Add the chicken pieces to the skillet and cook on all sides until nicely browned, about 10-12 minutes.
Pour the remaining marinade into the skillet and add 100 ml of water. Bring to a simmer, then reduce heat and cook until the sauce thickens, about 5-6 minutes.
In a small bowl, whisk the cornstarch with a little water to form a slurry. Pour the slurry into the chicken and cook until the sauce has thickened to your liking. Season with salt and pepper to taste, if needed.
Garnish the Peking chicken with fresh green onions and serve with rice or your favorite vegetables.
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