Select fresh, undamaged grape leaves, then thoroughly rinse them in cold water.
Bring a large pot of water to a boil, then briefly blanch the grape leaves, one at a time, for 20-30 seconds, until softened. Drain and let them cool.
In another pot, combine the water, vinegar, salt, and sugar. Bring to a boil, stirring until all ingredients are completely dissolved.
Peel and halve the garlic cloves. Place the bay leaves, mustard seeds, black peppercorns, and cloves at the bottom of a jar.
Layer the grape leaves in the jar, alternating with the spices and garlic.
Pour the hot sweet and sour brine over the leaves, ensuring they are completely submerged.
Let the jar cool to room temperature, then refrigerate for at least 3 days to allow the flavors to meld.
Your sweet and sour pickled grape leaves are ready! Use them for making stuffed grape leaves (dolmades) or other Mediterranean dishes.
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