Halve the pomegranate. Gently tap the skin with a spoon to release the seeds. Remove any white pith.
In a small saucepan, combine the white wine vinegar, water, honey, and salt. Heat over medium heat, stirring until the honey and salt are completely dissolved.
In a clean, airtight jar, layer the pomegranate seeds. Add the cinnamon stick and black peppercorns.
Pour the hot pickling liquid over the pomegranate seeds, gently pressing down with a spoon to ensure they are fully submerged.
Let the jar cool to room temperature for about 30 minutes, then seal and refrigerate for at least 24 hours to allow the flavors to meld.
Use the sweet and sour pickled pomegranate seeds to enhance salads, complement cheeses, or garnish meat dishes. Store in the refrigerator for up to 1-2 weeks.
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