Thoroughly wash the pimento peppers, then halve them and remove the seeds.
In a large saucepan, combine the water, vinegar, salt, and sugar. Bring to a boil, stirring until all ingredients are completely dissolved.
Peel and halve the garlic cloves. Place the bay leaves, mustard seeds, black peppercorns, and cloves at the bottom of a jar.
Pack the pimento peppers into the jar, layering them with the spices and garlic.
Pour the hot sweet and sour brine into the jar, ensuring the peppers are completely submerged.
Let the jar cool to room temperature, then refrigerate for at least 48 hours to allow the flavors to meld.
The sweet and sour pickled pimento peppers are ready! Enjoy them on their own, in salads, or as a complement to sandwiches.
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